
The chemistry to mitigate or eliminate the carbon footprint of human activities and provide “a permanent inexhaustible supply of carbon containing fuels or products, which subsequently can be combusted or used without increasing the carbon dioxide content of the atmosphere” has been developed by University of California chemists Professor George A. Olah and Professor G.K. Surya Prakash, according to U.S. Patent Application 20090285739. Their discoveries could even lead to a reduction of carbon dioxide content in the atmosphere.
Thus, the current lifestyles that rely extensively on conventional carbon containing fuels and products can continue indefinitely without harming the environment to preserve and even improve the earth’s atmosphere for the benefit of future generations.
This method includes an initial step of capturing carbon dioxide and then chemically recycling it to form and carbon containing fuels or products. Olah’s and Prakas’ discoveries offer a feasible way to mitigate the carbon footprint caused by human activities by not limiting or prohibiting the use of carbon containing fuels for energy generation, production of transportation fuels and varied derived materials and products, but instead by preparing such fuels and related carbon containing products from carbon dioxide that is captured from plants that generate it or by the removal of carbon dioxide from the atmosphere.
By capturing and chemically recycling CO2 emissions, a neutral or in some case a negative carbon footprint is achieved. This is feasible by recycling preferentially higher concentrations of industrial and natural CO2 sources and emissions but also by capturing and recycling an equivalent amount, or on occasion even greater amounts, of CO2 directly from atmosphere or air itself.
Of course, nature itself recycles carbon dioxide through agricultural plants and trees, but the combustion and use of oil and other fossil fuels has simply overloaded the system so that it cannot keep up with the amounts of carbon dioxide that are generated. The invention recognizes this shortcoming and now seeks to assist nature in this admirable recycling project.
By first capturing carbon dioxide from the environment, or at least by preventing further amounts from being discharged, and then by converting the captured carbon dioxide to a carbon based fuel or feedstock, future generations can continue to utilize such fuels and feedstocks as well as the products made from such chemicals, without causing further harm to the environment. Thus, future sources of these fuels and products can be provided without increasing the emission of carbon dioxide or its resulting carbon footprint. The products can be used in an environmentally neutral manner.
In particular, the CO2 that is captured and recovered can be used to produce suitable and renewable fuels such as methanol or dimethyl ether as well their derived products and materials
At present, the world is facing an oil crisis, caused by rapid depletion of natural resources and our increasing use of technology that requires fuel. National oil reserves presently provide a cushion for major oil or natural gas emergencies and help to avoid disastrous disruptions caused by natural causes, as well as by geopolitical or economic interruption of these sources.
The United States government has recognized this crisis; the Strategic Petroleum Reserve (SPR) was established in the 1970s to maintain an emergency oil supply, and the Energy Policy Act of 2005 directed the Secretary of Energy to fill the SPR to its 1 billion barrel capacity. Unfortunately, there have been several challenges to meeting this directive, including emergency situations like Hurricane Katrina, the on-going turbulence in the middle-east, and the overall oil shortage. Furthermore, storage of oil, by its nature, poses several safety issues, for example, its extreme flammability.
Olah and Prakash advocate storing methanol and dimethyl ether instead of oil. They have developed a convenient storage of methanol and/or dimethyl ether as strategic reserve fuels that can be readily and effectively stored in natural or man-made storage facilities from which they can be readily withdrawn for use. As methanol and dimethyl ether can essentially be produced from recycling CO2 from any sources, including the air, with hydrogen provided by water and utilizing any energy source, the present method of stockpiling of fuel and energy reserves in the form of methanol and/or dimethyl ether provides a convenient new way for safeguarding against energy and fuel emergencies and shortages, according to U.S. Patent Application 20090320356.
Stockpiling of methanol offers several advantages over stockpiling oil. First, methanol is far less flammable than oil and other hydrocarbons, having a boiling point of 64.6.degree. C. (54.degree. F.) at atmospheric pressure. Gasoline, in contrast, will ignite at temperatures below freezing. Also, methanol is naturally present and found essentially non-toxic in plant and animal studies. For humans, methanol is safe at low concentrations. As a result of methanol’s ready availability and relative safety, the storage thereof is far less expensive than oil and other fuels. Due to its physical properties, methanol is also easy to transport.
Dimethyl ether can also be conveniently stored and handled in the same manner as liquefied petroleum gas. Dimethyl ether is a gas at room temperature, so that it is pressurized to a liquid to facilitate handling. It generally should be stored in pressurized tanks or similar vessels.
One of the world’s preeminent scholars of hydrocarbon chemistry, Professor George Olah received the 1994 Nobel Prize in Chemistry for groundbreaking work on superacids and his observations of carbocations. Olah devised a way to keep the transient carbocations around long enough to study their properties. What he found has lead to new discoveries, new fields of research and countless applications.
Professor Olah studies a wide range of synthetic and mechanistic organic chemistry with emphasis on hydrocarbon chemistry. He is currently investigating electrophilic (protic) solvation, superelectrophilic activation, which allows new applications in alkylation, acylation and many other reactions. Olah has made significant research contributions to the practical development of improved lead-free gasoline, cleaner high-octane gas and other promising nonpolluting fuels, as well as many chemical processes now used in pharmaceutical and industrial chemistry. His research has also led to the development of a new kind of fuel cell, called the direct liquid methanol fuel cell, that is a highly efficient and convenient source of electricity.
His most recent research centers on the conversion of two greenhouse gases, carbon dioxide and methane, into useful fuels and products, investigations driven by his long-standing interest in energy and environmental issues.
To find new solutions to these pressing issues, Olah is working to develop new, cleaner and renewable fuels, based on methanol, to replace diminishing oil reserves while reducing levels of greenhouse gases. (The Methanol Economy Concept). The concept of the Methanol Economy process presents significant advantages and great economic possibilities. In the Methanol Economy process, methanol is used as (1) convenient energy storage medium, which allows convenient and safe storage and handling; (2) readily transported and dispensed fuel, including for internal combustion engines and methanol fuel cells; and (3) feedstock for synthetic hydrocarbons and their products currently obtained from oil and gas resources, including polymers and even single cell proteins, which can be used for animal feed or human consumption. The environmental benefits obtained by disclosed chemical recycling of carbon dioxide results in mitigating the global warming to ensure the well being of future generations
The figure shows the chemicals and products that are derived from methanol.
The separation and use of atmospheric CO2 allows chemical recycling of CO2 as a renewable and unlimited source of carbon. CO2 absorption facilities can be placed proximate to a hydrogen production site to enable subsequent methanol synthesis. Although the CO2 content in the atmosphere is low (only 0.037%), the atmosphere offers an abundant and unlimited supply when CO2 is recycled. For using atmospheric carbon dioxide efficiently, CO2 absorption facilities are needed. This can be addressed by using efficient CO2 absorbents such as polyethyleneimines, polyvinylpyridines, polyvinylpyrroles, etc., on suitable nano-structured solid carriers (e.g., active carbon, polymers, silica or alumina), which allow absorption of even the low concentration of atmospheric CO2.
On March 11th, Prof. Olah at the California NanoSystems Institute delivered a talk about his discoveries in the area of carbocations, for which he won the Nobel Prize, and his current interest work to develop new cleaner and renewable fuels based on methanol. The lecture was entitled “Efficient Carbon Capture, Storage and Recycling Based on the Foundations of Lewis, Meerwein, Wittig and Winstein, for a Sustainable Future.”
Professor Olah and Professor Prakash detail their discoveries in a series of recently published patent applications:
20100022671 PRODUCING METHANOL AND ITS PRODUCTS EXCLUSIVELY FROM GEOTHERMAL SOURCES AND THEIR ENERGY
20090320356 STOCKPILING METHANOL AND/OR DIMETHYL ETHER FOR FUEL AND ENERGY RESERVES
20090293348 EFFICIENT AND SELECTIVE CHEMICAL RECYCLING OF CARBON DIOXIDE TO METHANOL, DIMETHYL ETHER AND DERIVED PRODUCTS
20090293348 EFFICIENT AND SELECTIVE CHEMICAL RECYCLING OF CARBON DIOXIDE TO METHANOL, DIMETHYL ETHER AND DERIVED PRODUCTS
20090285739 MITIGATING OR ELIMINATING THE CARBON FOOTPRINT OF HUMAN ACTIVITIES
20090172997 ENVIRONMENTALLY FRIENDLY TERNARY TRANSPORTATION FLEX-FUEL OF GASOLINE, METHANOL AND BIOETHANOL
